Application of substituted N-arylpyrroles in the corrosion protection of aluminium in hydrochloric acid

The inhibiting action of N-arylpyrroles on aluminium in 0.17 mol dm^–3 hydrochloric acid solution, in the temperature range 20–60 °C, was studied using potentiodynamic and electrochemical impedence spectroscopy techniques. The inhibiting efficiency of both investigated compounds 1-(2-fluorophenyl)-2,5-dimethylpyrrole (compound A) and 1-(2-fluorophenyl)-2,5-dimethylpyrrole-3-carbaldehyde (compound B) slightly increases with increasing temperature of the corrosive solution. Inhibitor adsorption on the elecrode surface decreases the apparent activation energy of the hydrogen evolution reaction. Compound A follows the Temkin adsorption isotherm, while its carbaldehyde derivative follows the Langmuir isotherm. The results of the apparent energy of activation and the standard free energy of adsorption point to stronger chemisorption of the compound A. However, due to additional condensation of molecules with carbaldehyde groups on the electrode surface, the carbaldehyde derivative exhibits even better inhibiting efficiency than compound A. The kinetic corrosion parameters, analysed in terms of the impedance data, show a satisfactory agreement with those obtained by the potentiodynamic method.     

液化气球罐焊缝H2S应力腐蚀裂纹的返修补焊

对宁夏炼油厂一台200m3低合金钢球罐H2S应力腐蚀裂纹采用气刨打磨后补焊的返修方法表明，碳弧气刨时的骤热不会使裂纹向纵深扩展，只是必须在补焊前将返修部位焊缝两侧各100mm范围内打磨至完全露出金属光泽，以便彻底消除裂纹源，避免补焊时再产生新的微小裂纹。若返修深度不大于罐壁厚度的二分之一，则不必进行射线探伤检查，只须进行100％的超声波检查，在水压试验前后对返修部位进行100％磁粉探伤则是非常必要的。     

利用控制头酸化测试联作的新方法

采用采油树进行酸化作业，安全可靠，但在原钻机试油过程中，采用采油树酸化作业工作量大而繁重，存在一些不便之处。利用控制头替代采油树酸化作业，可以解决困扰酸化施工时来回倒换井口的难题，并且可以缩短试油周期，减少管柱起下钻次数，为含硫化氢油气井的施工提供了安全保障。1997年以来，在塔中26井、塔中126井利用控制头实施酸化作业并获得成功，为酸化测试联作及超深高含硫井的施工积累了实际经验。     

气敏薄膜的光学机理研究

本文根据光传输理论导出介导消光系数，折射率与介质电磁参数，光波频率，电偶极子浓度及迁移率等的关系，分析了光激发与增加气敏介质的氧吸附的规律，结合实验说明气敏薄膜的光学变化机制。     

补偿式光纤F—P干涉仪的信号处理系统

本文提出并研制成补偿式光纤F-P干涉仪信号处理系统,提出了用来测量微小位移信号的三种方法及电路,即透射峰时间间隔测量法、光脉冲基波幅度测量法(精密整流法)、鉴相法。测试结果表明:时间间隔测量法,它的最大灵敏度达到0.26纳米/微秒;精密整流法,最大灵敏度为2.38纳米/伏特。     

利用扫描电镜研究三维电极主电极表面腐蚀状况

借助扫描电镜（SEM）对不同实验条件下的三维电极主电极表面腐蚀状况进行研究。结果表明，三维电极主极阳极的内侧腐蚀程度远大于其外侧，水样性质、电极材料性质对电极的腐蚀程度有很大的影响，不锈钢做三维电极主电极优于铝、铁电极。为三维电极主电极的选材提供了一定的理论依据。     

电脉冲快速退火对铁基非晶合金性能的影响

采用大电流交流脉冲对非晶Ｆｅ７８Ｂ１３Ｓｉ９合金进行了去应力退火。初步探讨了电脉冲加热对加热速率和该合金内应力释放、退火脆化以及最终软磁性影响的基本规律。结果表明：电脉冲加热可以得到远高于常规退火的加热速率，选择合适工艺参数可使非晶合金内应力释放９０％，软磁性（Ｈ＿ｃ和Ｂ＿ｓ）达常规退火后的９５％以上，与此同时使合金的延性（断裂应变ε＿ｆ）维持在０．９以上，从而有望实现非晶合金磁性与延性的合理配合。     

三种M3Al型金属间化合物的低温热腐蚀

Na_2SO_4沉积物显著地加速Fe_3Al、Ni_3Al和Ti_3Al在600℃模拟燃气气氛中的腐蚀.腐蚀产物为M与Al的氧化物和硫化物的混合物.Fe_3Al和Ti_3Al的耐蚀性优于Ni_3Al因为Fe_3Al腐蚀产物中有一含高Al_2O_3的内层在Ti_3Al上则有由TiO_2和NbO_2组成的中间层而Ni_3Al的腐蚀产物的内层含有大量硫化镍有利于Ni的向外传输Na_2SO_4中添加NaCl对三种M_3Al的腐蚀过程无明显影响     

Hardness-stress-strain correlation in aluminium—A simpler alternative to visioplasticity in metal forming

Local stress and strain variations in the deformation zone can be ascertained by measuring hardness. Hardness is correlated with strain and stress. The expressions discussed later are useful in determining the local variations in stress and strain from hardness measurement. It is a simple method compared to visioplasticity. One can estimate the forces required for a forming process. It helps in the choice of equipment, design of tooling and selection of lubricant for the particular process.